86
|
Answers:
- The signal at 3.56 ppm has a multiplicity M
of 7 (6 equivalent neighboring protons)
Did you come up with a different answer? Check page
73
again for an explanation of the cause of multiplet formation.
- JCH,CH3
= JCH3,CH
= 6.1 Hz,
since the coupling between the methyl protons and the methine proton is
mediated by the same bond electrons as the reverse coupling between the
methine proton and the methyl protons.
| Complementary coupling constants (i.e.,
JAX and JXA)
are always identical! |
-
|
Signal |
|
Dn
[Hz] |
|
Dd
[ppm] |
|
Irel |
| 0 |
0 |
0 |
20 |
| 1/1' |
6.1 |
0.1 |
15 |
| 2/2' |
12.2 |
0.2 |
6 |
| 3/3' |
18.3 |
0.3 |
1 |
If your result is different, you should go back one step to page 83.
Otherwise continue to page 84!
|